Improbable as it may sound, it is possible to up transform the puny 3 volts available from a pair of D-cell batteries to any higher voltage you like. It is done with a DC-DC boost converter circuit, which employs inductors, capacitors, diodes, and high-speed electronic switches. (we really need those rare-earth mineral elements). You can get increases and discharges to 5,000 volts, but with very few milliamps from D-cells. A brief discharge of 5,000 volts hurts. Volts hurt and frighten, but it takes a high level of amps (0.1 or more) to kill a human.
A spark discharge after shuffling across a wool rug may generate tens of thousands of painful volts at just a very few milliamps. The voltage needed for a spark in air is approximately 3,000 volts per millimeter. On the other hand, a typical lightning bolt may have a voltage of around 300 million volts and a current of about 30,000 amps.
An imperfect anlogy: Think of high voltage as water pressure from a hole somewhere in a high dam. Amps is the measure of volume of water rushing through due to the size of a hole somewhere in the dam. You can stop most tiny leaks with finger pressure, but a large hole, especially in the high pressure bottom of the dam, will blow you away. A capacitor is the measure of the total volume of water held in the lake behind the dam.